EKOTEKS LIMITLERI

Limit values and fastness

If you have any questions about the individual test parameters please contact OEKO-TEX® secretariat or one of the OEKO-TEX® institutes and representative offices.

2016-07-25

Limit values and fastness, part 1

Product Class

I
Baby

II
in direct contact with skin

III
with no direct contact with skin

IV
Decoration material

pH value1

 

4.0 - 7.5

4.0 - 7.5

4.0 - 9.0

4.0 - 9.0

Formaldehyde [mg/kg]

Law 112

n.d.2

75

300

300

Extractable heavy-metals [mg/kg]

Sb (Antimony)

30.0

30.0

30.0

 

As (Arsenic)

0.2

1.0

1.0

1.0

Pb (Lead)

0.2

1.03

1.03

1.03

Cd (Cadmium)

0.1

0.1

0.1

0.1

Cr (Chromium)

1.0

2.0

2.0

2.04

Cr(VI)

under detection limit5

Co (Cobalt)

1.0

4.0

4.0

4.0

Cu (Copper)

25.06

50.06

50.06

50.06

Ni (Nickel)7

1.08

4.09

4.09

4.09

Hg (Mercury)

0.02

0.02

0.02

0.02

Heavy metals in digested sample [mg/kg]10

Pb (Lead)

90.0

90.03

90.03

90.03

Cd (Cadmium)

40.0

40.03

40.03

40.03

Pesticides [mg/kg]11, 12

Sum12

0.5

1.0

1.0

1.0

Chlorinated phenols [mg/kg]12

Pentachlorophenol (PCP)

0.05

0.5

0.5

0.5

Tetrachlorophenols (TeCP), Sum

0.05

0.5

0.5

0.5

Trichlorophenols (TrCP), Sum

0.2

2.0

2.0

2.0

Dichlorophenols (DCP), Sum

0.5

3.0

3.0

3.0

Monochlorophenols (MCP), Sum

0.5

3.0

3.0

3.0

Phthalates [w-%]13

Sum12

0.1

0.1

0.1

 

Sum without DINP12

     

0.1

 

Limit values and fastness, part 2

Product Class

I
Baby

II
in direct contact with skin

III
with no direct contact with skin

IV
Decoration material

Organic tin compounds [mg/kg]12

TBT, TPhT

0.5

1.0

1.0

1.0

DBT, DMT, DOT, DPhT, MBT, MOT, MMT, TeBT, TCyHT, TMT, TOT, TPT

1.0

2.0

2.0

2.0

Other chemical residues

OPP [mg/kg]12

50.0

100.0

100.0

100.0

Arylamines [mg/kg]12, 14

none5

SCCP [w-%]12

0.1

0.1

0.1

0.1

TCEP [w-%]12

0.1

0.1

0.1

0.1

DMFu [mg/kg]12

0.1

0.1

0.1

0.1

Colorants

Cleavable arylamines12

not used5

Carcinogens12

not used

Allergens12

not used5

Others12

not used5

Chlorinated benzenes and toluenes [mg/kg]12

Sum

1.0

1.0

1.0

1.0

Polycyclic aromatic hydrocarbons (PAH) [mg/kg]15

Benzo[a]pyrene

0.5

1.0

1.0

1.0

Benzo[e]pyrene

0.5

1.0

1.0

1.0

Benzo[a]anthracene

0.5

1.0

1.0

1.0

Chrysene

0.5

1.0

1.0

1.0

Benzo[b]fluoranthene

0.5

1.0

1.0

1.0

Benzo[j]fluoranthene

0.5

1.0

1.0

1.0

Benzo[k]fluoranthene

0.5

1.0

1.0

1.0

Dibenzo[a,h]anthracene

0.5

1.0

1.0

1.0

Sum12

5.0

10.0

10.0

10.0

Biological active products

 

none16

Flame retardant products

General

none16, 17

 

 

 

 

Limit values and fastness, part 3

Product Class

I
Baby

II
in direct contact with skin

III
with no direct contact with skin

IV
Decoration material

Solvent residues [w-%]18, 19

NMP

0.1

0.1

0.1

0.1

DMAc

0.1

0.1

0.1

0.1

DMF

0.1

0.1

0.1

0.1

Formamide

0.02

0.02

0.02

0.02

Surfactant, wetting agent residues [mg/kg]

OP, NP, Sum

< 10.0

< 10.0

< 10.0

< 10.0

OP, NP, OP(EO), NP(EO) Sum

< 100.0

< 100.0

< 100.0

< 100.0

PFC's, Perfluorinated Compounds12, 20

PFOS [μg/m2]

<1.0

<1.0

<1.0

<1.0

PFHpA [mg/kg]

0.05

0.1

0.1

0.5

PFOA [μg/m2]

<1.0

<1.0

<1.0

<1.0

PFNA [mg/kg]

0.05

0.1

0.1

0.5

PFDA [mg(kg]

0.05

0.1

0.1

0.5

PFUdA [mg/kg]

0.05

0.1

0.1

0.5

PFDoA [mg/kg]

0.05

0.1

0.1

0.5

PFTrDA [mg/kg]

0.05

0.1

0.1

0.5

PFTeDA [mg/kg]

0.05

0.1

0.1

0.5

UV stabilizers [w-%]

UV 320

     

0.1

UV 327

     

0.1

UV 328

     

0.1

UV 350

     

0.1

Colour fastness (staining)

To water

3

3

3

3

To acidic perspiration

3 - 4

3 - 4

3 - 4

3 - 4

To alkaline perspiration

3 - 4

3 - 4

3 - 4

3 - 4

To rubbing, dry21, 22

4

4

4

4

To saliva and perspiration

fast

     

 

 

 

 

 

 

 

 

 

Limit values and fastness, part 4

Product Class

I
Baby

II
in direct contact with skin

III
with no direct contact with skin

IV
Decoration material

Emission of volatiles [mg/m3]23

Formaldehyde [50-00-0]

0.1

0.1

0.1

0.1

Toluene [108-88-3]

0.1

0.1

0.1

0.1

Styrene [100-42-5]

0.005

0.005

0.005

0.005

Vinylcyclohexene [100-40-3]

0.002

0.002

0.002

0.002

4-Phenylcyclohexene [4994-16-5]

0.03

0.03

0.03

0.03

Butadiene [106-99-0]

0.002

0.002

0.002

0.002

Vinylchloride [75-01-4]

0.002

0.002

0.002

0.002

Aromatic hydrocarbons

0.3

0.3

0.3

0.3

Organic volatiles

0.5

0.5

0.5

0.5

Determination of odours

General

no abnormal odour24

SNV 195 651 (Modified)23

3

3

3

3

Banned fibres

Asbestos

not used

·         (1) Exceptions for products which must be treated wet during the further processing: 4.0 - 10.5; for foams: 4.0 - 9.0; for leather products in product class IV (coated or laminated): 3.5 - 9.0

·         (2) n.d. corresponds according to „Japanese Law 112“ test method with an absorbance unit less than 0.05 resp. <16 mg/kg

·         (3) No requirement for accessories made from glass

·         (4) For leather articles 10.0 mg/kg

·         (5) Quantification limits: for Cr(VI) 0.5 mg/kg, for Cr(VI) in leather 3.0 mg/kg, for arylamines 20 mg/kg, for dyestuffs 50 mg/kg

·         (6) No requirement for accessories made from inorganic materials

·         (7) Including the requirement by EC-Regulation 1907/2006

·         (8) For metallic accessories and metallized surfaces: 0.5 mg/kg

·         (9) For metallic accessories and metallized surfaces: 1.0 mg/kg

·         (10) Applicable to all non textile accessories and components as well as for spun dyed fibres and articles containing pigments

·         (11) For natural fibres only

·         (12) The individual substances are listed in Appendix 5

·         (13) For coated articles, plastisol prints, flexible foams, and accessories made from plastics

·         (14) For all materials containing polyurethane or other materials which may contain free carcinogenic arylamines

·         (15) For all synthetic fibres, yarns, or threads and for plastic materials

·         (16) With exception of treatments accepted by Oeko-Tex® (see actual list on http://www.oeko-tex.com)

·         (17) Accepted flame retardant products do not contain any of the banned flame retardant substances listed in Appendix 5 as active agent.

·         (18) Exception for products which must be treated hot (in wet or dry stage) during further processing: 3.0 %

·         (19) For fibre, yarns and coated articles, where solvents are used during production.

·         (20) For all materials with a water and oil repellent finish or coating

·         (21) No requirements for ’wash-out’ – articles

·         (22) For pigment, vat or sulphurous colorants a minimum grade of colour fastness to rubbing of 3 (dry) is acceptable

·         (23) For textile carpets, mattresses as well as foams and large coated articles not being used for clothing

·         (24) No odour from mould, high boiling fraction of petrol, fish, aromatic hydrocarbons or perfume

 

 

 

 

 

 

 

 

 

Compilation of the individual substances, Pesticides

Name

CAS-Nr.

2,4,5-T

93-76-5

2,4-D

94-75-7

Acetamiprid

135410-20-7, 160430-64-8

Aldicarb

116-06-3

Aldrine

309-00-2

Azinophosethyl

2642-71-9

Azinophosmethyl

86-50-0

Bromophos-ethyl

4824-78-6

Captafol

2425-06-1

Carbaryl

63-25-2

Chlordane

57-74-9

Chlordimeform

6164-98-3

Chlorfenvinphos

470-90-6

Clothianidin

210880-92-5

Coumaphos

56-72-4

Cyfluthrin

68359-37-5

Cyhalothrin

91465-08-6

Cypermethrin

52315-07-8

DEF

78-48-8

Deltamethrin

52918-63-5

DDD

53-19-0, 72-54-8

DDE

3424-82-6, 72-55-9

DDT

50-29-3, 789-02-6

Diazinon

333-41-5

Dichlorprop

120-36-5

Dicrotophos

141-66-2

Dieldrine

60-57-1

Dimethoate

60-51-5

Dinoseb, its salts and acetate

88-85-7 et al

Dinotefuran

165252-70-0

Endosulfan, α-

959-98-8

Endosulfan, β-

33213-65-9

Endrine

72-20-8

Esfenvalerate

66230-04-4

Fenvalerate

51630-58-1

Heptachlor

76-44-8

Heptachloroepoxide

1024-57-3

Hexachlorobenzene

118-74-1

Hexachlorcyclohexane, α-

319-84-6

Hexachlorcyclohexane, β-

319-85-7

Hexachlorcyclohexane, δ-

319-86-8

Imidacloprid

105827-78-9, 138261-41-3

Isodrine

465-73-6

Kelevane

4234-79-1

Kepone

143-50-0

Lindane

58-89-9

Malathion

121-75-5

MCPA

94-74-6

MCPB

94-81-5

Mecoprop

93-65-2

Metamidophos

10265-92-6

Methoxychlor

72-43-5

Mirex

2385-85-5

Monocrotophos

6923-22-4

Nitenpyram

150824-47-8, 120738-89-8

Parathion

56-38-2

Parathion-methyl

298-00-0

Perthane

72-56-0

Phosdrin/Mevinphos

7786-34-7

Propethamphos

31218-83-4

Profenophos

41198-08-7

Strobane

8001-50-1

Quinalphos

13593-03-8

Telodrine

297-78-9

Thiacloprid

111988-49-9

Thiamethoxam

153719-23-4

Toxaphene

8001-35-2

Trifluralin

1582-09-8

Compilation of the individual substances, Chlorinated phenols

Name

CAS-Nr.

Pentachlorophenol

87-86-5

2,3,5,6-Tetrachlorophenol

935-95-5

2,3,4,6-Tetrachlorophenol

58-90-2

2,3,4,5-Tetrachlorophenol

4901-51-3

2,3,4-Trichlorophenol

15950-66-0

2,3,5-Trichlorophenol

933-78-8

2,3,6-Trichlorophenol

933-75-5

2,4,5-Trichlorophenol

95-95-4

2,4,6-Trichlorophenol

88-06-2

3,4,5-Trichlorophenol

609-19-8

2,3-Dichlorophenol

576-24-9

2,4-Dichlorophenol

120-83-2

2,5-Dichlorophenol

583-78-8

2,6-Dichlorophenol

87-65-0

3,4-Dichlorophenol

95-77-2

3,5-Dichlorophenol

591-35-5

2-Chlorophenol

95-57-8

3-Chlorophenol

108-43-0

4-Chlorophenol

106-48-9

Compilation of the individual substances, Phthalates

Name

CAS-Nr.

Acronym

Butylbenzylphthalate

85-68-7

BBP

Dibutylphthalate

84-74-2

DBP

Di-(2-ethylhexyl)-phthalate

117-81-7

DEHP

Di-(2-methoxyethyl)-phthalate

117-82-8

DMEP

Di-C6-8-branched alkylphthalates, C7 rich

71888-89-6

DIHP

Di-C7-11-branched and linear alkylphthalates

68515-42-4

DHNUP

Di-cyclohexylphthalate

84-61-7

DCHP

Di-hexylphthalate, branched and linear

68515-50-4

DHxP

Di-iso-butylphthalate

84-69-5

DIBP

Di-iso-decylphthalate

26761-40-0, 68515-49-1

DIDP

Di-iso-hexylphthalate

71850-09-4

DIHxP

Di-iso-nonylphthalate

28553-12-0, 68515-48-0

DINP

Di-n-hexylphthalate

84-75-3

DHP

Di-n-octylphthalate

117-84-0

DNOP

Di-pentylphthalate (n-, iso-, or mixed)

131-18-0, 605-50-5, 776297-69-9, 84777-06-0

DPP

Compilation of the individual substances, Organic tin compounds

Name

Acronym

Dibutyltin

DBT

Dimethyltin

DMT

Dioctyltin

DOT

Diphenyltin

DPhT

Monomethyltin

MMT

Monobutyltin

MBT

Monooctyltin

MOT

Tetrabutyltin

TeBT

Tributyltin

TBT

Tricylcohexyltin

TCyHT

Trimethyltin

TMT

Trioctyltin

TOT

Triphenyltin

TPhT

Tripropyltin

TPT

Compilation of the individual substances, Arylamines having carcinogenic properties

Name

CAS-Nr.

MAK III, category 1

 

4-Aminobiphenyl

92-67-1

Benzidine

92-87-5

4-Chloro-o-toluidine

95-69-2

2-Naphthylamine

91-59-8

MAK III, category 2

 

o-Aminoazotoluene

97-56-3

2-Amino-4-nitrotoluene

99-55-8

p-Chloroaniline

106-47-8

2,4-Diaminoanisole

615-05-4

4,4’-Diaminodiphenylmethane

101-77-9

3.3’-Dichlorobenzidine

91-94-1

3,3’-Dimethoxybenzidine

119-90-4

3,3’-Dimethylbenzidine

119-93-7

4,4'-Methylenedi-o-toluidine

838-88-0

p-Cresidine

120-71-8

4,4’-Methylene-bis- (2-chloroaniline)

101-14-4

4,4’-Oxydianiline

101-80-4

4,4’-Thiodianiline

139-65-1

o-Toluidine

95-53-4

2,4-Toluylendiamine

95-80-7

2,4,5-Trimethylaniline

137-17-7

o-Anisidine (2-Methoxyaniline)

90-04-0

2,4-Xylidine

95-68-1

2,6-Xylidine

87-62-7

4-Aminoazobenzene

60-09-3

Compilation of the individual substances, Dyestuffs and pigments classified as carcinogenic

C.I. Generic Name

C.I. Structure number

CAS-Nr.

C.I. Acid Red 26

C.I. 16 150

3761-53-3

C.I. Basic Blue 26 (with ≥ 0.1 % Michler's ketone or base)

 

2580-56-5

C.I. Basic Red 9

C.I. 42 500

569-61-9

C.I. Basic Violet 3 (with ≥ 0.1 % Michler's ketone or base)

 

548-62-9

C.I. Basic Violet 14

C.I. 42 510

632-99-5

C.I. Direct Black 38

C.I. 30 235

1937-37-7

C.I. Direct Blue 6

C.I. 22 610

2602-46-2

C.I. Direct Red 28

C.I. 22 120

573-58-0

C.I. Disperse Blue 1

C.I. 64 500

2475-45-8

C.I. Disperse Orange 11

C.I. 60 700

82-28-0

C.I. Disperse Yellow 3

C.I. 11 855

2832-40-8

C.I. Pigment Red 104

C.I. 77 605

12656-85-8

C.I. Pigment Yellow 34

C.I. 77 603

1344-37-2

Compilation of the individual substances, Dyestuffs classified as allergenic

C.I. Generic Name

C.I. Structure number

CAS-Nr.

C.I. Disperse Blue 1

C.I. 64 500

2475-45-8

C.I. Disperse Blue 3

C.I. 61 505

2475-46-9

C.I. Disperse Blue 7

C.I. 62 500

3179-90-6

C.I. Disperse Blue 26

C.I. 63 305

 

C.I. Disperse Blue 35

 

12222-75-2

C.I. Disperse Blue 102

 

12222-97-8

C.I. Disperse Blue 106

 

12223-01-7

C.I. Disperse Blue 124

 

61951-51-7

C.I. Disperse Brown 1

 

23355-64-8

C.I. Disperse Orange 1

C.I. 11 080

2581-69-3

C.I. Disperse Orange 3

C.I. 11 005

730-40-5

C.I. Disperse Orange 37

C.I. 11 132

 

C.I. Disperse Orange 76

C.I. 11 132

 

C.I. Disperse Red 1

C.I. 11 110

2872-52-8

C.I. Disperse Red 11

C.I. 62 015

2872-48-2

C.I. Disperse Red 17

C.I. 11 210

3179-89-3

C.I. Disperse Yellow 1

C.I. 10 345

119-15-3

C.I. Disperse Yellow 3

C.I. 11 855

2832-40-8

C.I. Disperse Yellow 9

C.I. 10 375

6373-73-5

C.I. Disperse Yellow 39

   

C.I. Disperse Yellow 49

   

Compilation of the individual substances, Other banned dyestuffs

C.I. Generic Name

C.I. Structure number

CAS-Nr.

C.I. Disperse Orange 149

 

85136-74-9

C.I. Disperse Yellow 23

C.I. 26 070

6250-23-3

C.I. Basic Green 4 (oxolate)

 

2437-29-8, 18015-76-4

C.I. Basic Green 4 (chloride)

 

569-64-2

C.I. Basic Green 4 (free)

 

10309-95-2

Compilation of the individual substances, Chlorinated benzenes and toluenes

Chlorobenzene

Dichlorobenzenes

Trichlorobenzenes

Tetrachlorobenzenes

Pentachlorobenzenes

Hexachlorobenzene

Chlorotoluenes

Dichlorotoluenes

Trichlorotoluenes

Tetrachlorotoluenes

Pentachlorotoluene

Compilation of the individual substances, Polycyclic aromatic hydrocarbons (PAH)

Name

CAS-Nr.

Acenaphtene

83-32-9

Acenaphthylene

208-96-8

Anthracene

120-12-7

Benzo[a]anthracene

56-55-3

Benzo[a]pyrene

50-32-8

Benzo[b]fluoranthene

205-99-2

Benzo[e]pyrene

192-97-2

Benzo[ghi]perylene

191-24-2

Benzo[j]fluoranthene

205-82-3

Benzo[k]fluoranthene

207-08-9

Chrysene

218-01-9

Cyclopenta[c,d]pyrene

27208-37-3

Dibenzo[a,h]anthracene

53-70-3

Dibenzo[a,e]pyrene

192-65-4

Dibenzo[a,h]pyrene

189-64-0

Dibenzo[a,i]pyrene

189-55-9

Dibenzo[a,l]pyrene

191-30-0

Fluoranthene

206-44-0

Fluorene

86-73-7

Indeno[1,2,3-cd]pyrene

193-39-5

1-Methylpyrene

2381-21-7

Naphthalene

91-20-3

Phenanthrene

85-01-8

Pyrene

129-00-0

Compilation of the individual substances, Forbidden flame retardant substances

Name

CAS-Nr.

Acronym

2,2-bis(bromomethyl)-1,3-propanediol

3296-90-0

BBMP

Bis-(2,3-dibromopropyl)phosphate

5412-25-9

BIS

Boric acid

10043-35-3, 11113-50-1

 

Decabromodiphenylether

1163-19-5

decaBDE

Diboron trioxide

1303-86-2

 

Disodium tetraborate, anhydrous

1303-96-4, 1330-43-4, 12179-04-3

 

Heptabromodiphenylether

various

heptaBDE

Hexabromocyclododecane

25637-99-4

HBCDD

Hexabromodiphenylether

36483-60-0

hexaBDE

Octabromodiphenylether

32536-52-0

octaBDE

Pentabromodiphenylether

32534-81-9

penta BDE

Polybrominated biphenyles

59536-65-1

PBB

Short chain chlorinated paraffins (C10 - C13)

85535-84-8

SCCP

Tetraboron disodium heptaoxide, hydrate

12267-73-1

 

Tetrabromobisphenol A

79-94-7

TBBPA

Tetrabromodiphenylether

various

tetraBDE

Tri-(2,3-dibromopropyl)-phosphate

126-72-7

TRIS

Tris-(2-chloroethyl)phosphate

115-96-8

TCEP

Tris-(1,3-dichloro-2-propyl)phosphate

13674-87-8

TDCPP

Tris-(aziridinyl)-phosphinoxide

545-55-1

TEPA

Trixylylphosphate

25155-23-1

TXP

Compilation of the individual substances, Solvent residues

Name

CAS-Nr.

Acronym

1-Methyl-2-pyrrolidone

872-50-4

NMP

N,N-Dimethylacetamide

127-19-5

DMAc

Dimethylformamide

68-12-2

DMF

Formamide

75-12-7

 

Compilation of the individual substances, Surfactant, wetting agent residues

Name

CAS-Nr.

Acronym

Nonylphenol

various

NP

Octylphenol

various

OP

Octylphenolethoxylates

various

OP(EO)

Nonylphenolethoxylates

various

NP(EO)

Compilation of the individual substances, Other chemical residues

Name

CAS-Nr.

Acronym

o-Phenylphenol

90-43-7

OPP

Short chained chlorinated paraffines (C10 - C13)

85535-84-8

SCCP

Tris(2-chloroethyl)phosphate

115-96-8

TCEP

Dimethylfumarate

624-49-7

DMFu

Compilation of the individual substances, PFC's, Perfluorinated Compounds

Name

CAS-Nr.

Acronym

Perfluorooctane sulfonates

various

PFOS

Perfluoroheptanoic acids

various

PFHpA

Perfluorooctanoic acids

various

PFOA

Perfluorononanoic acids

various

PFNA

Perfluorodecanoic acids

various

PFDA

Henicosafluoroundecanoic acid

2058-94-8

PFUdA

Tricosafluorododecanoic acid

307-55-1

PFDoA

Pentacosafluorotridecanoic acid

72629-94-8

PFTrDA

Heptacosafluorotetradecanoic acid

376-06-7

PFTeDA

Compilation of the individual substances, UV stabilizers

Name

CAS-Nr.

Acronym

2-(2H-Benzotriazol-2-yl)-4-(tert-butyl)-6-(sec-butyl)phenol

36437-37-3

UV 350

2-(2H-Benzotriazol-2-yl)-4,6-di-tert-pentylphenol

25973-55-1

UV 328

2,4-Di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)phenol

3864-99-1

UV 327

2-Benzotriazol-2-yl-4,6-di-tert-butylphenol

3846-71-7

UV 320

 

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